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SIAM J. Appl. Math. 68, pp. 619-628 (10 pages)
Homogeneous Branched-Chain Explosions
A model of homogeneous explosions with competing branching and recombination processes due to Kapila is analyzed by singular perturbation methods. In this model, the concentration of radicals is very low during a long induction period that ends with a rapid radical-growth stage in which all the reactants are consumed as the radicals reach their peak concentrations. The sudden jump in radical concentration is then followed by a long period of chain termination. Based on an exact relation between the fuel concentration and a slowly varying combination of fuel and radicals, we find a composite of two matched asymptotic expansions providing very good agreement with the numerical solution. This approximation is compared to another composite obtained by the method of multiple self-adjusting scales. Both approximations seem to be similarly accurate provided the induction time is calculated beyond leading order.
© 2007 Society for Industrial and Applied Mathematics
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Received May 24, 2007
Accepted September 05, 2007
Published online December 07, 2007
Accepted September 05, 2007
Published online December 07, 2007
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